Modeling Atom‐Transfer Radical Polymerization of Butyl Acrylate
Identifieur interne : 004831 ( Main/Exploration ); précédent : 004830; suivant : 004832Modeling Atom‐Transfer Radical Polymerization of Butyl Acrylate
Auteurs : Hendrik Schroeder [Allemagne] ; Johannes Buback [États-Unis] ; Jens Schrooten [Allemagne] ; Michael Buback [Allemagne] ; Krzysztof Matyjaszewski [États-Unis]Source :
- Macromolecular Theory and Simulations [ 1022-1344 ] ; 2014-05.
Abstract
The kinetics of butyl acrylate (BA) atom‐transfer radical polymerization (ATRP) up to 2 000 bar has been modeled via PREDICI. A novel software package has been used in conjunction with PREDICI to perform automatic simulation and data processing within an extended range of polymerization conditions. The polymerization rate is enhanced with pressure, although to a weaker extent than in the ATRP of styrene and methyl methacrylate. Modeling suggests that intramolecular chain‐transfer in BA polymerization is significantly accelerated at high pressure.
Url:
DOI: 10.1002/mats.201300153
Affiliations:
- Allemagne, États-Unis
- Basse-Saxe, Pennsylvanie
- Göttingen, Pittsburgh
- Université Carnegie-Mellon, Université de Göttingen
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A novel software package has been used in conjunction with PREDICI to perform automatic simulation and data processing within an extended range of polymerization conditions. The polymerization rate is enhanced with pressure, although to a weaker extent than in the ATRP of styrene and methyl methacrylate. Modeling suggests that intramolecular chain‐transfer in BA polymerization is significantly accelerated at high pressure.</div></front></TEI><affiliations><list><country><li>Allemagne</li><li>États-Unis</li></country><region><li>Basse-Saxe</li><li>Pennsylvanie</li></region><settlement><li>Göttingen</li><li>Pittsburgh</li></settlement><orgName><li>Université Carnegie-Mellon</li><li>Université de Göttingen</li></orgName></list><tree><country name="Allemagne"><region name="Basse-Saxe"><name sortKey="Schroeder, Hendrik" sort="Schroeder, Hendrik" uniqKey="Schroeder H" first="Hendrik" last="Schroeder">Hendrik Schroeder</name></region><name sortKey="Buback, Michael" sort="Buback, Michael" uniqKey="Buback M" first="Michael" last="Buback">Michael Buback</name><name sortKey="Buback, Michael" sort="Buback, Michael" uniqKey="Buback M" first="Michael" last="Buback">Michael Buback</name><name sortKey="Schrooten, Jens" sort="Schrooten, Jens" uniqKey="Schrooten J" first="Jens" last="Schrooten">Jens Schrooten</name></country><country name="États-Unis"><region name="Pennsylvanie"><name sortKey="Buback, Johannes" sort="Buback, Johannes" uniqKey="Buback J" first="Johannes" last="Buback">Johannes Buback</name></region><name sortKey="Matyjaszewski, Krzysztof" sort="Matyjaszewski, Krzysztof" uniqKey="Matyjaszewski K" first="Krzysztof" last="Matyjaszewski">Krzysztof Matyjaszewski</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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